Bonding and Structure of Molecules and Solids / Edition 1

by David G. Pettifor, David Pettifor

Overview

This book explains the observed trends in the bonding and structure of molecules and solids within the models of the electronic structure. Emphasis is placed throughout on recent theoretical developments that link structural stability to the local topology or connectivity of the lattice through the moments of the electronic density of states. The chemically-intuitive Tight Binding approximation provides a unified treatment of the covalent bond in small molecules and extended solids, while the physically-intuitive Nearly-Free Electron approximation provides a natural description of the metallic bonds in sp-valent metals. Unlike the conventional reciprocal-space formulation of band theory, this modern real-space approach allows an immediate understanding of the origin of structural trends within the periodic table for the elements and the AB structure map for binary compounds. Although this unique book is aimed primarily at postgraduates in physics, chemistry, and materials science, a chapter on basic quantum mechanical concepts is included for those readers with little or no basic knowledge of the subject.

Product Details

ISBN-13:	9780198517863
Publisher:	Oxford University Press, USA
Publication date:	09/28/1995
Edition description:	New Edition
Pages:	272
Product dimensions:	9.13(w) x 6.13(h) x 0.63(d)

About the Author

Oxford University

Table of Contents

1. Experimental trends in bonding and structure
2. Quantum mechanical concepts
3. Bonding of molecules
4. Structure of molecules
5. Bonding of simple metals
6. Structures of simple metals
7. Bonding of transition metals and semiconductors
8. Structural trends within solids

Editorial Reviews

"The author explains the observed trends in the bonding and structure of molecules and solids within the framework of simple but predictive models of electronic structure. . . .Emphasis is placed throughout on recent theoretical developments that link structural stability to the local topology or connectivity of the lattice through the moments of the electronic density of states. . . .This modern real-space approach allows an immediate understanding of the origin of the structural trends within the periodic table for the elements and the AB structure map for binary compounds." —Zeitschrift für Kristallographie

From the Publisher