Chapter 1 | Basic Concepts | 1 |
1.1 | Introduction | 1 |
1.2 | The Elements | 1 |
1.3 | Matter and Energy | 2 |
1.4 | Properties | 3 |
1.5 | Classification of Matter | 3 |
1.6 | Representation of Elements | 5 |
1.7 | Laws, Hypotheses, and Theories | 6 |
Chapter 2 | Mathematical Methods in Chemistry | 10 |
2.1 | Introduction | 10 |
2.2 | Factor-Label Method | 10 |
2.3 | Metric System | 12 |
2.4 | Exponential Numbers | 16 |
2.5 | Significant Digits | 17 |
2.6 | Density | 21 |
2.7 | Temperature Scales | 23 |
Chapter 3 | Atoms and Atomic Masses | 38 |
3.1 | Introduction | 38 |
3.2 | Atomic Theory | 38 |
3.3 | Atomic Masses | 39 |
3.4 | Atomic Structure | 40 |
3.5 | Isotopes | 41 |
3.6 | Periodic Table | 42 |
Chapter 4 | Electronic Configuration of the Atom | 51 |
4.1 | Introduction | 51 |
4.2 | Bohr Theory | 51 |
4.3 | Quantum Numbers | 53 |
4.4 | Quantum Numbers and Energies of Electrons | 54 |
4.5 | Shells, Subshells, and Orbitals | 55 |
4.6 | Shapes of Orbitals | 58 |
4.7 | Buildup Principle | 58 |
4.8 | Electronic Structure and the Periodic Table | 60 |
Chapter 5 | Chemical Bonding | 67 |
5.1 | Introduction | 67 |
5.2 | Chemical Formulas | 67 |
5.3 | The Octet Rule | 68 |
5.4 | Ions | 69 |
5.5 | Electron Dot Notation | 71 |
5.6 | Covalent Bonding | 72 |
5.7 | Distinction Between Ionic and Covalent Bonding | 74 |
5.8 | Predicting the Nature of Bonding in Compounds | 75 |
5.9 | Detailed Electronic Configurations of Ions (Optional) | 76 |
Chapter 6 | Inorganic Nomenclature | 86 |
6.1 | Introduction | 86 |
6.2 | Binary Compounds of Nonmetals | 87 |
6.3 | Naming Ionic Compounds | 88 |
6.4 | Naming Inorganic Acids | 93 |
6.5 | Acid Salts | 94 |
6.6 | Hydrates | 94 |
Chapter 7 | Formula Calculations | 102 |
7.1 | Introduction | 102 |
7.2 | Molecules and Formula Units | 102 |
7.3 | Formula Masses | 103 |
7.4 | The Mole | 103 |
7.5 | Percent Composition of Compounds | 106 |
7.6 | Empirical Formulas | 107 |
7.7 | Molecular Formulas | 108 |
Chapter 8 | Chemical Equations | 120 |
8.1 | Introduction | 120 |
8.2 | Balancing Simple Equations | 121 |
8.3 | Predicting the Products of a Reaction | 122 |
Chapter 9 | Net Ionic Equations | 134 |
9.1 | Introduction | 134 |
9.2 | Writing Net Ionic Equations | 134 |
Chapter 10 | Stoichiometry | 142 |
10.1 | Mole-to-Mole Calculations | 142 |
10.2 | Calculations Involving Other Quantities | 143 |
10.3 | Limiting Quantities | 144 |
10.4 | Calculations Based on Net Ionic Equations | 147 |
10.5 | Heat Capacity and Heat of Reaction | 147 |
Chapter 11 | Molarity | 162 |
11.1 | Introduction | 162 |
11.2 | Molarity Calculations | 162 |
11.3 | Titration | 164 |
11.4 | Stoichiometry in Solution | 166 |
Chapter 12 | Gases | 173 |
12.1 | Introduction | 173 |
12.2 | Pressure of Gases | 173 |
12.3 | Boyle's Law | 174 |
12.4 | Graphical Representation of Data | 175 |
12.5 | Charles' Law | 177 |
12.6 | The Combined Gas Law | 180 |
12.7 | The Ideal Gas Law | 181 |
12.8 | Dalton's Law of Partial Pressures | 183 |
Chapter 13 | Kinetic Molecular Theory | 195 |
13.1 | Introduction | 195 |
13.2 | Postulates of the Kinetic Molecular Theory | 195 |
13.3 | Explanation of Gas Pressure, Boyle's Law, and Charles' Law | 196 |
13.4 | Graham's Law | 197 |
Chapter 14 | Oxidation and Reduction | 201 |
14.1 | Introduction | 201 |
14.2 | Assigning Oxidation Numbers | 201 |
14.3 | Periodic Relationships of Oxidation Numbers | 203 |
14.4 | Oxidation Numbers in Inorganic Nomenclature | 205 |
14.5 | Balancing Oxidation-Reduction Equations | 205 |
14.6 | Electrochemistry | 209 |
Chapter 15 | Solutions | 219 |
15.1 | Qualitative Concentration Terms | 219 |
15.2 | Molality | 219 |
15.3 | Mole Fraction | 220 |
15.4 | Equivalents | 221 |
15.5 | Normality | 222 |
15.6 | Equivalent Mass | 223 |
Chapter 16 | Rates and Equilibrium | 230 |
16.1 | Introduction | 230 |
16.2 | Rates of Chemical Reaction | 230 |
16.3 | Chemical Equilibrium | 232 |
16.4 | Equilibrium Constants | 234 |
Chapter 17 | Acid-Base Theory | 246 |
17.1 | Introduction | 246 |
17.2 | The Bronsted-Lowry Theory | 246 |
17.3 | Acid-Base Equilibrium | 248 |
17.4 | Autoionization of Water | 249 |
17.5 | The pH Scale | 250 |
17.6 | Buffer Solutions | 251 |
Chapter 18 | Organic Chemistry | 261 |
18.1 | Introduction | 261 |
18.2 | Bonding in Organic Compounds | 261 |
18.3 | Structural, Condensed, and Line Formulas | 262 |
18.4 | Hydrocarbons | 264 |
18.5 | Isomerism | 266 |
18.6 | Radicals and Functional Groups | 267 |
18.7 | Alcohols | 269 |
18.8 | Ethers | 270 |
18.9 | Aldehydes and Ketones | 271 |
18.10 | Acids and Esters | 271 |
18.11 | Amines | 272 |
18.12 | Amides | 272 |
Chapter 19 | Nuclear Reactions | 280 |
19.1 | Introduction | 280 |
19.2 | Natural Radioactivity | 280 |
19.3 | Half-Life | 282 |
19.4 | Radioactive Series | 283 |
19.5 | Nuclear Fission and Fusion | 284 |
19.6 | Nuclear Energy | 285 |
Appendix | Scientific Calculations | 292 |
A.1 | Scientific Algebra | 292 |
A.2 | Calculator Mathematics | 297 |
| Glossary | 312 |
| Practice Quizzes | 326 |
| Answers to Quizzes | 330 |
| Index | 335 |
| Conversions | 348 |
| Table of the Elements | 349 |
| Periodic Table | 350 |