Supercritical Fluid Technology: Theoretical and Applied Approaches in Analytical Chemistry

by Frank V. Bright, Mary Ellen P. McNally

Overview

Presents the current state of supercritical fluid technology and provides a link between researchers studying fundamental aspects of the science and those involved in the application of supercritical fluid technology to difficult chemical problems. Includes discussions of the fundamental aspects of solvation in supercritical fluid media and presents applications in spectroscopy, chromatography, extraction, and computer modeling. Also offers a discussion on regulatory agencies' roles in the implementation of supercritical fluid technology.

Product Details

ISBN-13:	9780841222205
Publisher:	American Chemical Society
Publication date:	05/28/1992
Series:	ACS Symposium Series
Pages:	374
Product dimensions:	6.20(w) x 8.90(h) x 0.90(d)

About the Author

State University of New York

E.I. du Pont de Nemours and Company

Table of Contents

Fundamental Studies and Applications of Supercritical Fluids: A Review
Raman Studies of Molecular Potential Energy Surface Changes in Supercritical Fluids
Influence of Solvent—Solute and Solute—Solute Clustering on Chemical Reactions in Supercritical Fluids
Elucidation of Solute—Fluid Interactions in Supercritical CF[3H by Steady-State and Time-Resolved Fluorescence Spectroscopy
Local Density Augmentation in Supercritical Solutions: A Comparison Between Fluorescence Spectroscopy and Molecular Dynamics Results
Investigation of Pyrene Excimer Formation in Supercritical CO[2
Fluorescence Investigation of Cosolvent—Solute Interactions in Supercritical Fluid Solutions
Investigations of Solute—Cosolvent Interactions in Supercritical Fluid Media: A Frequency-Domain Fluorescence Study
Laser Flash Photolysis Studies of Benzophenone in Supercritical CO[2
Spectroscopic Investigations of Organometallic Photochemistry in Supercritical Fluids
Use of Solvatochromic Dyes To Correlate Mobile Phase Solvent Strength to Chromatographic Retention in Supercritical Fluid Chromatography
Supercritical Fluid Extraction: New Directions and Understandings
Supercritical Fluid Extraction of Polar Analytes Using Modified CO[2 and In Situ Chemical Derivation
Supercritical Fluid Extraction in Environmental Analysis
Supercritical Fluid Extraction of Phenols from Water
Supercritical Fluid Extraction versus Soxhlet Sample Preparation: A Comparative Study for Extraction and Analysis of Organics in Solid Matrices
Relative Effect of Experimental Variables: Analytical Supercritical Fluid Extraction Efficiencies Correlations with Chromatographic Data
Supercritical Fluid Extraction: Developing a Turnkey Method
Supercritical Fluid Extraction in the Analytical Laboratory: A Technique Whose Time Has Come
Analytical Applications of Supercritical Fluid Extraction—Chromatography in the Coatings Industry
Systematic Multiparameter Strategies for Optimizing Supercritical Fluid Chromatographic Separations
Use of Modifiers in Supercritical Fluid Extraction

Editorial Reviews

For graduate and professional analytic chemists and chemical engineers, reviews the current state of supercritical fluid technology, and provides a link between researchers studying the fundamental aspects, and those involved in applying the technology in such fields as spectroscopy, chromatography, extraction, and computer modeling. Also discusses the role of regulatory agencies in implementing the technology. The 22 papers are from an April 1991 symposium in Atlanta, Georgia. Annotation c. Book News, Inc., Portland, OR (booknews.com)

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